Alkali-Activated Slag Coatings for Fire Protection of OPC Concrete

Abstract

During a fire, ordinary Portland cement (OPC) systems lose their mechanical properties. For this reason, it is important to find a way to protect it. This study suggested alternative uses of slag and phosphogypsum to produce coatings for fire-resistant applications. Five compositions of 10 mm thick alkali-activated slag coatings were investigated. In these compositions, different amounts of phosphogypsum (1%, 3%, 5%, 7%, and 10%) were used. In the first stage of this study, the residual compressive strength of samples with the coatings based on alkali-activated slag was compared to the results of OPC concrete samples without coatings. The experimental results showed that a higher residual compressive strength of 33.2–47.3 MPa OPC concrete was achieved for the samples with coatings. Meanwhile, the residual compressive strength of the uncoated samples was 32.37 MPa. In the second stage, OPC concrete samples were reinforced with fiberglass polymer (FRP) rods, and they had a similar positive effect on alkali-activated coatings. After exposure to higher temperatures, the pullout tests of the glass FRP bars showed that the adhesion strength was (9.44 MPa) 43.9% higher for the samples with coatings compared to the samples without coatings (6.56 MPa). Therefore, a higher bond strength can be maintained between concrete and FRP bars. Alkali-activated slag with 3% phosphogypsum can be used for the production of fire-resistant coating. These coatings could protect OPC concrete and reinforced concrete with glass FRP bars from fire.