Large-Area Biocompatible Random Laser for Wearable Applications

Abstract

Recently, wearable sensor technology has drawn attention to many health-related appliances due to its varied existing optical, electrical, and mechanical applications. Similarly, we have designed a simple and cheap lift-off fabrication technique for the realization of large-area biocompatible random lasers to customize wearable sensors. A large-area random microcavity comprises a matrix element polymethyl methacrylate (PMMA) in which rhodamine B (RhB, which acts as a gain medium) and gold nanorods (Au NRs, which offer plasmonic feedback) are incorporated via a spin-coating technique. In regards to the respective random lasing device residing on a heterogenous film (area > 100 cm2), upon optical excitation, coherent random lasing with a narrow linewidth (~0.4 nm) at a low threshold (~23 μJ/cm2 per pulse) was successfully attained. Here, we maneuvered the mechanical flexibility of the device to modify the spacing between the feedback agents (Au NRs), which tuned the average wavelength from 612.6 to 624 nm under bending while being a recoverable process. Moreover, the flexible film can potentially be used on human skin such as the finger to serve as a motion and relative-humidity sensor. This work demonstrates a designable and simple method to fabricate a large-area biocompatible random laser for wearable sensing.