Factors Affecting Hydrogen Adsorption in Metal–Organic Frameworks: A Short Review

Author:

Zeleňák VladimírORCID,Saldan IvanORCID

Abstract

Metal–organic frameworks (MOFs) have significant potential for hydrogen storage. The main benefit of MOFs is their reversible and high-rate hydrogen adsorption process, whereas their biggest disadvantage is related to their operation at very low temperatures. In this study, we describe selected examples of MOF structures studied for hydrogen adsorption and different factors affecting hydrogen adsorption in MOFs. Approaches to improving hydrogen uptake are reviewed, including surface area and pore volume, in addition to the value of isosteric enthalpy of hydrogen adsorption. Nanoconfinement of metal hydrides inside MOFs is proposed as a new approach to hydrogen storage. Conclusions regarding MOFs with incorporated metal nanoparticles, which may be used as nanoscaffolds and/or H2 sorbents, are summarized as prospects for the near future.

Funder

The Scientific Grant Agency

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

Reference193 articles.

1. Communication from the Commission to the European Parliament, the European Council, the Council, the European Economic and Social Committee and the Committee of the Regions. The European Green Deal, COM/2019/640 finalhttps://eur-lex.europa.eu/legal-content/EN/ALL/?uri=COM:2019:640:FIN

2. A European Green Deal. Striving to Be the First Climate-Neutral Continenthttps://ec.europa.eu/info/strategy/priorities-2019-2024/european-green-deal

3. Communication from the Commission to the European Parliament, the European Council, the Council, the European Economic and Social Committee and the Committee of the Regions. A Hydrogen Strategy for a Climate-Neutral Europe, COM/2020/301 Finalhttps://ec.europa.eu/energy/sites/ener/files/hydrogen_strategy.pdf

4. Hydrogen Roadmap Europe, A Sustainable Pathway for the European energy Transitionhttps://www.fch.europa.eu/sites/default/files/Hydrogen%20Roadmap%20Europe_Report.pdf

5. Tokyo Olympic Torch to be powered by hydrogen, In H2 View. 26 March 2021https://www.h2-view.com/story/tokyo-olympic-torch-to-be-powered-by-hydrogen/

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