Factors Affecting Hydrogen Adsorption in Metal–Organic Frameworks: A Short Review

Author:

Zeleňák VladimírORCID,Saldan IvanORCID

Abstract

Metal–organic frameworks (MOFs) have significant potential for hydrogen storage. The main benefit of MOFs is their reversible and high-rate hydrogen adsorption process, whereas their biggest disadvantage is related to their operation at very low temperatures. In this study, we describe selected examples of MOF structures studied for hydrogen adsorption and different factors affecting hydrogen adsorption in MOFs. Approaches to improving hydrogen uptake are reviewed, including surface area and pore volume, in addition to the value of isosteric enthalpy of hydrogen adsorption. Nanoconfinement of metal hydrides inside MOFs is proposed as a new approach to hydrogen storage. Conclusions regarding MOFs with incorporated metal nanoparticles, which may be used as nanoscaffolds and/or H2 sorbents, are summarized as prospects for the near future.

Funder

The Scientific Grant Agency

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

Reference193 articles.

1. Communication from the Commission to the European Parliament, the European Council, the Council, the European Economic and Social Committee and the Committee of the Regions. The European Green Deal, COM/2019/640 finalhttps://eur-lex.europa.eu/legal-content/EN/ALL/?uri=COM:2019:640:FIN

2. A European Green Deal. Striving to Be the First Climate-Neutral Continenthttps://ec.europa.eu/info/strategy/priorities-2019-2024/european-green-deal

3. Communication from the Commission to the European Parliament, the European Council, the Council, the European Economic and Social Committee and the Committee of the Regions. A Hydrogen Strategy for a Climate-Neutral Europe, COM/2020/301 Finalhttps://ec.europa.eu/energy/sites/ener/files/hydrogen_strategy.pdf

4. Hydrogen Roadmap Europe, A Sustainable Pathway for the European energy Transitionhttps://www.fch.europa.eu/sites/default/files/Hydrogen%20Roadmap%20Europe_Report.pdf

5. Tokyo Olympic Torch to be powered by hydrogen, In H2 View. 26 March 2021https://www.h2-view.com/story/tokyo-olympic-torch-to-be-powered-by-hydrogen/

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3