Synthesis and Characterization of Coconut-Derived Graphene Nano Sheet (GNS) and Its Properties in Nickel/GNS and Zinc/GNS Hybrid Electrodes

Author:

Tarigan Kerista12ORCID,Siburian Rikson23ORCID,Anshori Isa45ORCID,Widiarti Nuni6,Alias Yatimah Binti78,Goh Boon Tong9ORCID,Huang Jingfeng10ORCID,Bahfie Fathan11ORCID,Manik Yosia Gopas Oetama23ORCID,Goei Ronn10ORCID,Tok Alfred Iing Yoong10ORCID

Affiliation:

1. Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Sumatera Utara, Medan 20155, Indonesia

2. Carbon and Frankincense Research Center, Universitas Sumatera Utara, Medan 20155, Indonesia

3. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sumatera Utara, Medan 20155, Indonesia

4. Lab on Chip Laboratory, Department of Biomedical Engineering, Bandung Institute of Technology, Bandung 40116, Indonesia

5. Research Center for Nanoscience and Nanotechnology (RCNN), Bandung Institute of Technology, Bandung 40132, Indonesia

6. Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Negeri Semarang, Semarang 50229, Indonesia

7. Department of Chemistry, Faculty of Science, Universiti Malaya, Kuala Lumpur 50603, Malaysia

8. Centre for Ionic Liquids (UMCiL), University of Malaya, Kuala Lumpur 50603, Malaysia

9. Low Dimensional Materials Research Centre, Department of Physics, Faculty of Science, University of Malaya, Kuala Lumpur 50603, Malaysia

10. School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

11. Research Center of Mining Technology—National Research and Innovation Agency of Indonesia, Jl. Sutami Km 15, Tanjung Bintang, South Lampung, Lampung 35361, Indonesia

Abstract

This study introduces a sustainable method of producing a graphene nano sheet (GNS) from coconut shells and investigates its application in GNS, Ni/GNS, and Zn/GNS electrodes for advanced energy storage devices. The GNS was synthesized in a scalable manner using a pyrolysis and impregnation technique, with its successful synthesis verified by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), Raman spectroscopy, and electrical conductivity measurement characterizations. The study highlights the enhanced performance of Zn/GNS electrodes, which outperform both pure GNS and Ni/GNS variants. This superior performance is attributed to the smaller particle size of Zn (mean = 2.356 µm) compared to Ni (mean = 3.09 µm) and Zn’s more favourable electron configuration for electron transfer. These findings demonstrate the potential of bio-derived GNS composites as efficient, high-performance electrodes, paving the way for more sustainable and cost-effective energy storage solutions.

Funder

Riset Kolaborasi Indonesia, Universitas Sumatera Utara Tahun Anggaran 2024 SKEMA—C

Publisher

MDPI AG

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