The Role of Diamonds Dispersed in Ferronematic Liquid Crystals on Structural Properties

Author:

Bury Peter1,Veveričík Marek1,Černobila František1,Tomašovičová Natália2ORCID,Lacková Veronika2ORCID,Kónyová Katarína2ORCID,Šafařík Ivo34,Petrenko Viktor56ORCID,Tomchuk Oleksandr78ORCID,Timko Milan2ORCID,Kopčanský Peter2ORCID

Affiliation:

1. Department of Physics, Žilina University, Univerzitná 1, 010 26 Žilina, Slovakia

2. Institute of Experimental Physics, Slovak Academy of Sciences, Watsonova 47, 040 01 Košice, Slovakia

3. Department of Nanobiotechnology, Institute of Soil Biology and Biogeochemistry, Biology Centre, Czech Academy of Science, Na Sádkách 7, 370 05 České Budějovice, Czech Republic

4. Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacký University, Šlechtitelů 27, 783 71 Olomouc, Czech Republic

5. IBERBASQUE, Basque Foundation for Science, Plaza Euskadi 5, 48009 Bilbao, Spain

6. BC Materials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

7. ISIS Neutron and Muon Source, Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX, UK

8. Department of Soft Matter Research, The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, 31-342 Kraków, Poland

Abstract

A study of the role of diamond nanoparticles on 5CB liquid crystal composites with Fe3O4 nanoparticles is presented. Composite ferronematic systems based on the nematic liquid crystal 5CB doped with Fe3O4 magnetic nanoparticles and additionally bound to diamond nanoparticles (DNPs), of a volume concentration of 3.2 mg/mL, 1.6 mg/mL and 0.32 mg/mL, were investigated using both magneto-optical effect and surface acoustic waves (SAWs) to study the role of diamond nanoparticles on the structural properties of ferronematic liquid crystals. The responses of light transmission and SAW attenuation to an external magnetic field were investigated experimentally under a linearly increasing and decreasing magnetic field, respectively. Investigations of the phase transition temperature shift of individual composites were also performed. The experimental results highlighted a decrease in the threshold field in the ferronematic LC composites compared to the pure 5CB as well as its further decrease after mixing Fe3O4 with diamond powder. Concerning the transition temperature, its increase with an increase in the volume fraction of both kinds of nanoparticles was registered. The role of diamond nanoparticles in the structural changes and the large residual light transition and/or attenuation (memory effect) were also observed. The presented results confirmed the potential of diamond nanoparticles in nematic composites to modify their properties which could lead to final applications.

Funder

VEGA project

Slovak Research and Development Agency

Structural Funds of the EU, Ministry of Education, Slovakia

Publisher

MDPI AG

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