Effects of Rare-Earth Elements Doping on Micro-Structure and Fluorescence Performances of Fluorapatite

Abstract

For purposes of optimizing the microstructure and fluorescence properties of rare-earth elements (REEs)-doped fluorapatites (FAps), various kinds of REEs (La, Pr, Sm, Eu, Gd, Ho, Er, and Yb) with the concentration of 2~20 mol.% have been inserted into the FAps framework via hydrothermal method, in order to investigate the influential mechanism of the REEs on the crystal structure, morphology, and fluorescence under the excitation of the near-ultraviolet light of the FAps. Experimental results show that the wavelength of the emitted light of the REEs-doped FAps is decided by the type of REEs. Unlike the Pr/Yb- and Ho-doped FAps and with the fluorescence of red and green emitted light, respectively, the Er-doped FAps show a blue light emission with wavelengths of 296, 401, and 505 nm, which is, moreover, different with the Eu-doped Faps, showing an orange light emission with wavelengths of 490, 594, and 697 nm. The emission luminous color is related to the lattice defects of the FAps doped with the various types and the effective doping concentration of the REEs. The luminous intensity increases with the increase in the effective doping concentration of the REEs. Nevertheless, the formation of rare-earth fluoride results in the decrease in the effective doping concentration of the REEs and the luminous intensity. The FAps with an effective doping concentration of 7 mol.% Er and 3 mol.% Eu show relative excellent fluorescence properties.