In-Situ Oxidative Polymerization of Pyrrole Composited with Cellulose Nanocrystal by Reactive Ink-Jet Printing on Fiber Substrates

Abstract

A simple and novel method for the deposition of polypyrrole (PPy) and cellulose nanocrystal (CNC) composites on different fiber substrates by reactive ink-jet printing was proposed. PPy/CNCs composites were successfully prepared, and the surface resistance of conductive layer deposited on different fiber substrates is the least when the monomer concentration is 0.6 M. PPy/CNCs were deposited on polyethylene terephthalate (PET) to form a conductive layer by adding polyvinyl alcohol (PVA), and the optimum sintering temperature is 100 °C (monomer/PVA ratio 4.0, conductivity 0.769 S cm−1). The PPy/CNCs conductive layer deposited on the paper has the lowest surface resistance and the best adhesion, and the surface resistance of PPy/CNCs conductive layer decreases first and then increases with the increase of sulfonate concentration. Moreover, the volume of anion in sulfonate will affect the arrangement and aggregation of PPy molecular chain in composite materials. Appropriate sulfonate doping can improve the conductivity and stability of conductive paper, and the maximum conductivity is 0.813 S cm−1. Three devices based on PPy/CNCs conductive paper were proposed and fabricated. Therefore, this ink-jet printing provides a new method for the preparation of conductive materials, sensors, energy storage and electromagnetic shielding, etc.