The Effect of Different Dosages of TESPT on Metal Friction and Metal Wear in the Mixing Process

Abstract

Studies show that the dispersion of silica in the mixing process is an important factor affecting the wear of the mixing chamber. As the most important mixing equipment, the long operational life of the internal mixer will cause wear in the rotor and chamber of the internal mixer. This wear increases the gap between the rotor and chamber of the internal mixer, reduces the mixing performance, weakens the dispersion of packing, and adversely affects the quality of the rubber produced. Therefore, it is important to investigate the metal wear in the mixing process. This article examines the effect of the addition of different amounts of silane coupling agents on metal friction and wear during the mixing process. The silane coupling agent has two functions. The first is to make the surface of the silica hydrophobic, enabling it to combine the inorganic matrix of the silica with the organic matrix of the rubber; the second is to inhibit the aggregation of the silica in the rubber. In the present study, we examine (1) the influence of different formulations on the friction and wear of the metal in the mixing chamber from the perspective of formulation technology, and (2) the correlation between corrosion wear and abrasive wear. It is found that a rubber compound with 6 phr of TESPT has the lowest metal wear and that adding more TESPT does not affect the degree of metal wear. As the amount of TESPT increases, the proportion of abrasive wear decreases, while the proportion of corrosive wear increases, reaching a maximum of 20.7%. In our study we found that abrasive wear is the predominant wear mechanism of a rubber compound on metal. In contrast, the corrosive wear caused by high-temperature water vapor still occupies a large proportion of the total wear. Therefore, improving silica dispersion and reducing abrasive wear are extremely important methods to protect the mixing chamber. However, the corrosion of metals by high-temperature water vapor should also be considered when preparing for the mixing process.