Effects of Zinc Addition on the Corrosion Behavior of Pre-Filmed Alloy 690 in Borated and Lithiated Water at 330 °C

Author:

Jeon Soon-HyeokORCID,Lim Dong-Seok,Choi Jinsoo,Song Kyu-Min,Lee Jong-HyeonORCID,Hur Do-HaengORCID

Abstract

The purpose of this work is to quantify the effects of dissolved zinc cations on corrosion and release rates from a pre-filmed Alloy 690 steam generator tubing material that was subsequently exposed to water containing zinc. The corrosion tests were performed in circulating 2 ppm Li and 1000 ppm B water without and with 60 ppb zinc at 330 °C. Gravimetric analyses and oxide characterization revealed that the corrosion rates, release rates, and oxide thicknesses decreased by subsequent exposure of the pre-filmed Alloy 690 to zinc. These benefits are attributed to the formation of a chromium-rich inner oxide layer incorporating zinc.

Funder

National Research Foundation of Korea

Central Research Institute of Korea Hydro & Nuclear Power Co., Ltd of the Republic of Korea

Publisher

MDPI AG

Subject

General Materials Science

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