Investigating Salt Precipitation in Continuous Supercritical Water Gasification of Biomass

Abstract

The formation of solid deposits in the process of supercritical water gasification (SCWG) is one of the main problems hindering the commercial application of the process. Seven experiments were conducted with the grass Reed Canary Grass with different preheating temperatures, but all ended early due to the formation of solid deposits (maximum operation of 3.8 h). The position of solid deposits in the lab plant changed with the variation in the temperature profile. Since the formation of solid deposits consisting of salts, coke, and corrosion products is a severe issue that needs to be resolved in order to enable long-time operation, inner temperature measurements were conducted to determine the temperature range that corresponds with the zone of solid formation. The temperature range was found to be 400 to 440 °C. Wherever this temperature was first reached solid deposits occurred in the system that led to blockage of the flow. Additional to the influence of the temperature, the influence of the flow direction (up-flow or down-flow) on the operation of the continuous SCWG plant was examined. If salts are not separated from the system sufficiently, up-flow reactors should be avoided because they amplify the accumulation of solid deposits leading to a shortened operation time. The heating concept coupled with the salt separation needs to be redesigned in order to separate the salts before entering the gasification reactors. Outside of the determined temperature zone no deposition was visible. Thus, even though the gasification efficiency was low it could be shown that the operation was limited to the deposits forming in the heating section and not by incomplete gasification in the reactor where T > 600 °C.