Abstract
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by elemental analyses and HR-MS. Owing to its chelating properties, this new terpyridine molecule was tested as a ligand in a metal-catalyzed reaction: The Ni-catalyzed dimerization of benzyl bromide.
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Cited by
8 articles.
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1. Synthesis, characterization and structural analysis of complexes from 2,2′:6′,2′′-terpyridine derivatives with transition metals;Acta Crystallographica Section C Structural Chemistry;2024-05-16
2. Crystal structures, electron spin resonance, and thermogravimetric analysis of three mixed-valence copper cyanide polymers;Acta Crystallographica Section C Structural Chemistry;2024-05-01
3. 4′-(3,5-Dimethoxy-4-propargyloxyphenyl)-2,2′:6′,2″-terpyridine;Molbank;2022-12-14
4. Chalcone- and flavone-based novel terpyridine metal complexes: Synthesis, electrochemical, photophysical, photovoltaic and computational studies;Dyes and Pigments;2022-05
5. 4′-(5-N-Propylthiophen-2-yl)-2,2′:6′,2″-terpyridine;Molbank;2021-01-21