Cellulose Nanofibrils and Tubular Halloysite as Enhanced Strength Gelation Agents

Author:

Vinokurov Vladimir,Novikov AndreiORCID,Rodnova Valentina,Anikushin Boris,Kotelev Mikhail,Ivanov EvgeniiORCID,Lvov YuriORCID

Abstract

Silica gels are widely employed in water shutoff services, making them an essential tool in oil well management. Silica nanoparticles may serve as a strengthening additive for polymer hydrogels. In this study, we look at this statement from a different angle: What additives could be used to increase the strength of silica gels? Colloidal silica gels were prepared with various additives, and gel strength was measured by a Veiler–Rebinder apparatus. We found that cellulose nanofibrils considerably increase the gel strength (from 20–25 to 35–40 kPa), which is comparable with the industrial anionic polymer Praestol 2540. Cellulose nanofibrils can be produced from cheap industrial-grade cellulose with low-cost industrial chemicals and could be partially replaced by the even less expensive halloysite nanoclay. Cellulose nanofibrils produced from renewable sources and naturally occurring halloysite nanoclay could be used as complementary reinforcing agents.

Funder

Ministry of Science and Higher Education of Russia

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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