Removing Pb(II) Ions from Aqueous Solution by a Promising Absorbent of Tannin-Immobilized Cellulose Microspheres

Abstract

Tannin/cellulose microspheres (T/C) were successfully prepared via a facile homogeneous reaction in a water/oil (W/O) emulsion for removing Pb(II) ions from aqueous solution. The structure of the microspheres was characterized by scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, and a zeta potential test. The effects of pH, adsorbent dosage, contact time, and temperature on adsorption ability were investigated. The results showed that T/C microspheres could combine Pb(II)ions via electrostatic attractions and physical adsorption. Adsorption kinetics could be better described by the pseudo-second-order kinetic model. The adsorption behaviors were in agreement with the Langmuir adsorption isotherm model with a fitting correlation coefficient of 0.9992. The maximum adsorption capacity was 23.75 mg/g from the Langmuir isotherm evaluation at 308K with an initial pH of 5. The results suggested that tannin/cellulose microspheres could be a low-cost and effective adsorbent for removing Pb(II) ions from aqueous solution.