Abstract
The data on the existence and physicochemical characteristics of uncharged single element chemical compounds formed by nitrogen atoms and containing more than two nuclides of this element (from N4 to N120, oligomeric and polymeric polynitrogens) have been systematized and generalized. It has been noticed that these data have a predominantly predictive character and were obtained mainly using quantum chemical calculations of various levels (HF, DFT, MP, CCSD etc.). The possibility of the practical application of these single element compounds has been considered. The review mainly covers articles published in the last 25 years. The bibliography contains 128 references.
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Computer Science Applications,Spectroscopy,Molecular Biology,General Medicine,Catalysis
Reference128 articles.
1. Nitrogenhttps://en.wikipedia.org/wiki/Nitrogen
2. Chemistry of the Elements;Greenwood,2012
3. The Nature of the Chemical Bond;Pauling,1960
4. On the thermodynamic and kinetic features of the reductive fixation of molecular nitrogen;Liechtenstein;Zh. Fiz. Khim.,1970
5. The nitrogen (N4) molecule and its metastability
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