Synthesis and Structure of a Coordination Polymer of Ni(II) with 2-(4-Bromophenoxy)acetohydrazide-Reference-Cited by-同舟云学术

Synthesis and Structure of a Coordination Polymer of Ni(II) with 2-(4-Bromophenoxy)acetohydrazide

Published:2024-05-08 Issue:2 Volume:2024 Page:M1819
ISSN:1422-8599
Container-title:Molbank
language:en
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Author:

Martsynko Оlena¹,Nesterkina Mariia²^ORCID,Finik Оlena³,Tsymbaliuk Kyrylo¹³,Dyakonenko Viktoriya⁴^ORCID,Shishkina Svitlana⁴⁵,Kravchenko Iryna²

Affiliation:

1. Department of Inorganic Chemistry and Chemical Education, Odesa I.I. Mechnikov National University, 65082 Odessa, Ukraine

2. Helmholtz Institute for Pharmaceutical Research Saarland (HIPS)-Helmholtz Centre for Infection Research (HZI), Campus Building E 8.1, 66123 Saarbrücken, Germany

3. Limited Liability Company “INSPECTORAT UKRAINE”, 65044 Odessa, Ukraine

4. State Scientific Institution “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 61001 Kharkov, Ukraine

5. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Akademika Kukharya Street 5, 02660 Kyiv, Ukraine

Abstract

The coordination compound [NiCl2L(2-PrOH)]n (where L is 2-(4-bromophenoxy)acetohydrazide; 2-PrOH is isopropanol) was obtained for the first time. The complex was characterized by means of elemental analyses, molar conductance, thermogravimetric analysis, IR spectroscopy, and single crystal X-ray diffraction analysis. It was determined that the coordination compound exhibits a polymeric structure. The complexing agent is six-coordinated, and its distorted octahedron forms due to the bidentate coordination of 2-(4-bromophenoxy)acetohydrazide through the carbonyl oxygen atom and the amine nitrogen. The oxygen of the molecule of isopropanol, the chlorine atom, and two chlorine atoms serve as bridges between two metal atoms.

Publisher

MDPI AG

Link

https://www.mdpi.com/1422-8599/2024/2/M1819/pdf

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