Assessment of Chemical Properties, Heavy Metals, and Metalloid Contamination in Floodplain Soils under the Influence of Copper Mining: A Case Study of Sibay, Southern Urals

Abstract

The ecotoxicological condition of soils around mining areas is most often unsatisfactory, which affects entire ecosystems and human health. This research sought to analyze the morphological, agrochemical properties, and content of heavy metals (Cd, Cu, Zn) and metalloids (As) of soils located in a floodplain. The study was conducted within the city of Sibay (Republic of Bashkortostan, Russia). The soil samples were collected from the floodplains of the rivers Karagayly and Khudolaz. According to morphological studies, the soil cover was represented by the Lithic Leptosols, Stagnic Phaeozems, and Fluvisols. The results showed that the soils were characterized by high values of organic matter, potassium, and low levels of phosphorus. Soils that were located away from the city in the Karagayly River were not contaminated. However, the floodplain areas pertaining to the urban district and located near the quarries were characterized by severe anthropogenic soil pollution, disrupted integrity of the soil cover, decreased vegetation, and accumulating labile forms of heavy metals and metalloids. The highest degree of pollution was observed in the floodplain soil of the river Khudolaz where all elements exceeded the maximum permissible concentration (MPC) level. Soils in the floodplain of the Karagayly river were marked by an increased degree of contamination of Zn: exceeding MPC by 1.6 times. With the trend toward an arid climate, the ecotoxicological condition of floodplain soils is an important challenge.