Densities, Viscosities and Excess Properties for Dimethyl Sulfoxide with Diethylene Glycol and Methyldiethanolamine at Different Temperatures

Abstract

Densities and viscosities of the binary systems dimethylsulfoxide with diethylene glycol and methyldiethanolamine were measured at temperatures ranging from 293.15 to 313.15 K, at atmospheric pressure and over the entire composition range. The experimental density data was correlated as a function of composition using Belda’s and Herraez’s equations, and as a function of temperature and composition using the models of Emmerling et al. and Gonzalez-Olmos-Iglesias. The viscosity results were fitted to the Grunberg-Nissan, Heric-Brewer, Wilson, Noda, and Ishida and Eyring-NRTL equations. The values of viscosity deviation (Δη), excess molar volume (VE), partial molar volumes (V1¯ and V2¯) and apparent molar volume (Vφ,1 and Vφ,2) were determined. The excess functions of the binary systems were fitted to the polynomial equations. The values of thermodynamic functions of activation of viscous flow were calculated and discussed.