Catalytic Conversion of Sugars into Lactic Acid via a RuOx/MoS2 Catalyst

Abstract

The catalytic transformation of sugars into lactic acid has shown great potential for the scalable utilization of renewable biomass. Herein, RuOx/MoS2 catalysts were synthesized with the assistance of CaO for the one-pot conversion of glucose to lactic acid. Under the reaction conditions of 120 °C and 1 MPa O2, a 96.6% glucose conversion and a 54.3% lactic acid selectivity were realized in the one-pot catalytic reaction, with relatively high stability after four successive cycles. This catalytic system was also effective for the conversion of many other carbohydrate substrates, such as fructose, xylose and cellulose (selectivity 68.9%, 78.2% and 50.6%, respectively). According to catalyst characterizations and conditional experiments, the highly dispersed RuOx species on the surface of MoS2, together with OH−, promoted isomerization, retro-aldol condensation, dehydration and hydration reactions, resulting in a relatively high lactic acid yield for sugar conversions.