Improving the Photocatalytic Performance of Porous Ceria under Visible Light Illumination via Mn Incorporation

Abstract

Porous cerium oxide (ceria) nanoparticles were prepared with and without manganese (Mn) by using the flash combustion technique. Samples with different loadings (Ce/Mn ratio ranged from 100 to 10) were prepared by using a one-step process and water only as a solvent. Moreover, citric acid was utilized as a fuel in an aqueous medium, and the overall synthesis mixture was dried at 100 °C overnight and then calcinated at 550 °C for 3 h. The obtained final solid product was characterized by inductively coupled plasma (ICP), X-ray powder diffraction (XRD), diffuse reflectance ultraviolet-visible spectroscopy (DR-UV-Vis), and scanning electron microscopy (SEM), which was coupled with Energy Dispersive X-Ray Analysis (EDX), high resolution transmission electron microscopy (HR-TEM), and photoluminescence (PL) analysis. The characterization data showed that Mn ions were totally incorporated into the framework of ceria up to the applied loading. Under visible light illumination, the photocatalytic activity of the prepared samples was tested in the decolorization reaction of methyl green (MG) dye (wavelength greater than 425 nm). The results showed that increasing Mn content improved the photocatalytic activity of ceria. The sample with a Ce/Mn ratio of 10 performed 1.8 times better than bare porous ceria. Finally, the reusability of the best-performing sample was investigated in four consecutive runs without treatment, and slight deactivation was monitored after the fourth run.