Author:
Liu Yangzi,Liu Jiayu,Xing Zhihao,Zhang Xueqian,Luo Chen,Yan Wenjuan,Jin Xin
Abstract
Glycerol hydrogenolysis represents one of the most promising technologies for future bio-refineries. In this context, kinetic modeling provides key quantitative assessment of the significance of various reactions for process development. However, as of present, there are only limited studies on detailed kinetic modeling of glycerol conversion to 1,2-propanediol, ethylene glycol and other alcoholic products. In this work, a comprehensive summary on kinetic modeling of glycerol hydrogenolysis has been conducted to reveal the possible mechanism involved in the activation of the C-H and C-O bond in glycerol molecules. In particular, power law and Langmuir–Hinshelwood model types have been critically discussed with mechanistic insights. The outcome of this review article will offer alternative views on the scale-up design of glycerol hydrogenolysis to glycols, as well as hydrogenolysis of various other bio-derived compounds to value-added chemicals.
Funder
National Natural Science Foundation
Natural Science Foundation of Shandong Province
Postdoctoral Research Funding of Shandong Province
Qingdao Postdoctoral Research Funding
Development Fund of State Key Laboratory of Heavy Oil Processing
China University of Petroleum
Subject
Physical and Theoretical Chemistry,Catalysis,General Environmental Science
Cited by
1 articles.
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