Hydrothermal Co-Crystallization of Novel Copper Tungstate-Strontium Titanate Crystal Composite for Enhanced Photocatalytic Activity and Increased Electron–Hole Recombination Time

Abstract

The development of catalysts continues to have a significant influence on science today since we can utilize them to efficiently destroy some contaminants. A study in this field is justified because there is a dearth of comprehensive literature on the creation of SrTiO3-based photocatalysts. Related to this topic, here we report the facile preparation of a structure-modified SrTiO3 photocatalyst, by incorporating CuWO4. Within the case of the CuWO4-modified samples (0.5–3 wt% nominal CuWO4 content), the photo-oxidation of phenol, as a contaminant, was more than two times higher than the initial SrTiO3. However, the photocatalytic activity does not change linearly with increasing CuWO4 content, and the CWS2.5 (2.5 wt% nominal CuWO4 content and 4.25 wt% measured content) has the highest photo-activity under the applied conditions. The reason for the better activity was the increased recombination time of charge separation on the catalyst surface. Slower recombination can result in more water being oxidized to hydroxyl radicals, leading to the faster decomposition of the phenol.