Catalytic Activity of Ni Based Materials Prepared by Different Methods for Hydrogen Production via the Water Gas Shift Reaction

Abstract

Water gas shift reactions (WGS) were evaluated over Ni/CeO2 and Ni/CeSmO catalysts for hydrogen production. The effects of catalyst preparation method and Sm loading were investigated. The Ni/ceria and Ni/CeSmO catalysts were synthesized by combustion, sol gel and sol gel-combustion method. After WGS tests, the catalysts were determined the carbon deposition by thermogravimetric analysis. The thermogravimetric analysis and temperature programmed NH3 desorption showed that addition of Sm promoter made higher the weak acid sites and lower the amount of carbon deposition than the unpromoted catalyst due to it being easily removed. CO chemisorption result indicated that Ni/Ce5%SmO catalyst prepared by combustion method has the highest Ni metal dispersion and metallic surface area compared to the other catalysts. The enhancement of WGS activity of this catalyst is due to more surface active sites being exposed to reactants. Furthermore, H2-temperature programmed reduction analysis confirmed an easiest reduction of this catalyst. This behavior accelerates the redox process at the ceria surface and enhances the oxygen vacancy concentration. The catalytic activity measurements exhibited that the optimum Sm loading was 5% wt. and the best catalyst preparation was the combustion method. The high surface area and small crystallite size of the 5%Ni/Ce5%SmO (combustion) catalyst resulted in sufficient dispersion, which closely related to the WGS activity of the catalyst.