Affiliation:
1. State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
Abstract
Metal ion doping is the most widely used means to improve the photocatalytic performance of semiconductor materials, which can adjust the band gap, broaden the range of optical response and construct impurity levels. The high efficiency modified NaTaO3 perovskite catalyst with good structural and catalytic properties was synthesized by a simple hydrothermal reaction method. A variety of analysis and testing techniques, such as XRD, SEM, DRS, XPS and EPR, were used to analyze the structure properties of the prepared materials. The results show that the influence mechanism of different metal introduction on the structure and properties of the NaTaO3 perovskite was different. Metal doping promoted the bond angle of Ta-O-Ta close to 180°, which restrains the recombination of the photogenerated electron-holes in the crystal. As Ce is introduced into the perovskite, the CeO2 forms and agglomerates around the perovskite, which improves the electron transport performance. With the narrower band gap, the Ce-modified perovskite shows that the degradation rate of ARS is 84% after 180 min of photoreaction. The species of h+, O2− and ·OH play different roles in improving the performance of the photocatalytic degradation process.
Funder
Natural Science Foundation of Ningxia Province
National Natural Science Foundation of China
Subject
Physical and Theoretical Chemistry,Catalysis,General Environmental Science