BiVO4 Photoanodes Modified with Synergetic Effects between Heterojunction Functionalized FeCoOx and Plasma Au Nanoparticles

Abstract

The design and development of high-performance photoanodes are the key to efficient photoelectrochemical (PEC) water splitting. Based on the carrier transfer characteristics and localized surface plasmon resonance effect of noble metals, gold nanoparticles (AuNPs) have been used to improve the performance of photoanodes. In this study, a novel efficient composite BiVO4/Au/FeCoOx photoanode is constructed, and the quantitative analysis of its performance is systematically conducted. The results reveal that the co-modification of AuNPs and FeCoOx plays a synergetic role in enhancing the absorption of ultraviolet and visible light of BiVO4, which is mainly attributed to the localized surface plasmon resonance effect induced by AuNPs and the extended light absorption edge position induced by the BiVO4/FeCoOx heterojunction. The BiVO4/Au/FeCoOx photoanode exhibits a high photocurrent density of 4.11 mA cm−2 at 1.23 V versus RHE at room temperature under AM 1.5 G illumination, which corresponds to a 299% increase compared to a pristine BiVO4 photoanode. These results provide practical support for the design and preparation of PEC photoanodes decorated with AuNPs and FeCoOx.