Laser Irradiation-Induced Pt-Based Bimetallic Alloy Nanostructures without Chemical Reducing Agents for Hydrogen Evolution Reaction

Author:

Hu Taiping12,Fan Yisong345,Ye Yixing1,Cai Yunyu1,Liu Jun1,Ma Yao1,Li Pengfei1,Liang Changhao12

Affiliation:

1. Key Laboratory of Materials Physics and Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

2. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China

3. Anhui Provincial Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

4. Advanced Laser Technology Laboratory of Anhui Province, National University of Defense Technology, Hefei 230037, China

5. School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China

Abstract

Binary metallic alloy nanomaterials (NMs) have received significant attention because of their widespread application in photoelectrocatalysis, electronics, and engineering. Although various synthetic methods have been adopted to prepare binary alloy NMs, the formation of bimetallic alloy NMs by irradiating the mixed solutions of metal salts and metal powders, using a nanosecond pulsed laser in the absence of any reducing agent, is rarely reported. Herein, we report a simple method to fabricate PtX (X = Ag, Cu, Co, Ni) alloy NMs by laser irradiation. Taking PtAg alloys as an example, we present the growth dynamics of the PtAg alloys by laser irradiating a mixture solution of bulk Pt and AgNO3. The experimental process and evidenced characterization indicate that the photothermal evaporation induced by laser irradiation can cause the fragmentation of the bulk Pt into smaller parts, which alloy with Ag atoms extracted from Ag+ by solvated electrons (e−aq) and free radicals (Haq). These alloys were used as electrocatalysts for the hydrogen evolution reaction (HER), proving their potential application. Notably, in a 0.5 M H2SO4 solution, the PtNi alloy exhibited higher HER activity (44 mV at 10 mA/cm−2) compared to the untreated bulk Pt (72 mV). Our work provides unique insights into the growth processing of valuable Pt-based bimetallic alloy NMs by laser-assisted metallic alloying, which paves a path for the development of bimetallic alloy electrocatalysts.

Funder

National Natural Science Foundation of China

Youth Innovation Promotion Association of CAS

Collaborative Innovation Program of Hefei Science Center of CAS

Plan for Anhui Major Provincial Science & Technology Project

HFIPS Director’s Fund, Chinese Academy of Sciences

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Catalysis,General Environmental Science

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