Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal

Author:

Vujančević Jelena1ORCID,Andričević Pavao23ORCID,Djokić Veljko24ORCID,Blagojević Vladimir5,Pavlović Vera P.6,Ćirković Jovana7,Horváth Endre28ORCID,Forró László29ORCID,Karoui Abdennaceur10,Pavlović Vladimir B.11,Janaćković Djordje4

Affiliation:

1. Institute of Technical Sciences of SASA, Knez Mihailova 35/IV, 11000 Belgrade, Serbia

2. Ecole Polytechnique Fédérale de Lausanne, Laboratory of Physics of Complex Matter, CH-1015 Lausanne, Switzerland

3. Department of Physics, Technical University of Denmark, DTU Risø Campus, 4000 Lyngby, Denmark

4. Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade, Serbia

5. TBP Software, Solunska 11, 11000 Belgrade, Serbia

6. Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11120 Belgrade, Serbia

7. University of Belgrade, Institute for Multidisciplinary Research, Kneza Višeslava 1, 11000 Belgrade, Serbia

8. Haute école du Paysage, D’ingénierie et D’architecture de Genève—HEPIA, 1202 Genève, Switzerland

9. University of Notre Dame, 204A Nieuwland Science Hall, Notre Dame, IN 46556, USA

10. Department of Physics, North Carolina Central University, 1801 Fayetteville St., Durham, NC 27707, USA

11. Faculty of Agriculture, University of Belgrade, Nemanjina 6, 11080 Belgrade-Zemun, Serbia

Abstract

In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.

Funder

Ministry of Education, Science and Technological Development of the Republic of Serbia

National Science Foundation grants

Department of Energy/National Nuclear Security Administration

Swiss National Science Foundation

ERC advanced grant “PICOPROP”

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Catalysis,General Environmental Science

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