Integrated Modeling of the Catalytic Aquathermolysis Process to Evaluate the Efficiency in a Porous Medium by the Example of a Carbonate Extra-Viscous Oil Field

Author:

Minkhanov Ilgiz F.1,Chalin Vladislav V.1,Tazeev Aidar R.1ORCID,Bolotov Alexander V.1,Mukhamatdinov Irek I.1ORCID,Sitnov Sergey A.1,Vakhin Alexey V.1ORCID,Varfolomeev Mikhail A.1ORCID,Kudryashov Sergey I.2,Afanasiev Igor S.2,Solovyev Alexey V.2,Sansiev Georgiy V.2,Antonenko Dmitry A.2,Dubrovin Kirill A.2,Simakov Iaroslav O.2

Affiliation:

1. Institute of Geology and Petroleum Technologies, Kazan (Volga Region) Federal University, 18 Kremlyovskaya Str., 420008 Kazan, Russia

2. JSC Zarubezhneft, Basmanniy Municipal District Intra-City Area, 9 Armianskiy Pereulok, 101000 Moscow, Russia

Abstract

In order to evaluate the efficiency of the catalytic aquathermolysis process, physical modeling was carried out on bituminous sediments of Paleocene–Miocene carbonate rocks, characterized by the presence of open and closed fractures. In this context, three filtration experiments were performed on an unextracted reservoir model with extra-viscous oil (EVO). Prior to the experiments, the mineral composition of the rock was determined by X-ray diffraction analysis (XRD) and the content of organic matter and coking products was determined before and after the experiment by thermogravimetric analysis (TGA) as well as the group composition of oil (SARA) before and after the experiment by nuclear magnetic resonance (NMR), gas composition at the fluid separation line, and oil displacement coefficient (ODC). The results of the conducted experiments show that the efficiency of displacement of extraviscous oil could be significantly increased by the use of a solvent and the combined use of a solvent and a catalyst (+9.3% and +17.1% of the oil displacement coefficient, respectively), which is associated with the processes of oil refining.

Funder

the Russian Science Foundation

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Catalysis,General Environmental Science

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