Biodiesel Production from Waste Oil Catalysed by Metal-Organic Framework (MOF-5): Insights on Activity and Mechanism-Reference-Cited by-同舟云学术

Biodiesel Production from Waste Oil Catalysed by Metal-Organic Framework (MOF-5): Insights on Activity and Mechanism

Published:2023-02-28 Issue:3 Volume:13 Page:503
ISSN:2073-4344
Container-title:Catalysts
language:en
Short-container-title:Catalysts

Author:

Taddeo Francesco¹^ORCID,Vitiello Rosa¹^ORCID,Russo Vincenzo¹^ORCID,Tesser Riccardo¹^ORCID,Turco Rosa¹²^ORCID,Di Serio Martino¹^ORCID

Affiliation:

1. Department of Chemical Sciences, Monte Sant’Angelo Campus, University of Naples “Federico II”, Via Cinthia 4, 80126 Naples, Italy

2. Institute for Polymers, Composites and Biomaterials, National Council of Research, Via Campi Flegrei 34, 80078 Pozzuoli, Italy

Abstract

The activity of MOF-5-based solids has been exploited in the simultaneous transesterification and esterification of acid vegetable oils. For this purpose, three different types of MOF-5 have been synthesized and characterized, and then tested in the above-mentioned reactions. It has been demonstrated that the “regular MOF-5” was a suitable catalyst for biodiesel synthesis from waste oil also, rich in FFA (Free Fatty Acids). Moreover, to identify the true structure that acts in the reactions and possible structural modifications due to the presence of alcohols, proper studies have been performed. The results have evidenced a distortion of the regular structure of MOF-5 due to the breakage of some zinc bonds between the cluster and organic framework.

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Catalysis,General Environmental Science

Link

https://www.mdpi.com/2073-4344/13/3/503/pdf

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