Flexible Ultraviolet Sensor Based on Zinc Oxide Nanoparticle Powder

Abstract

Zinc oxide nanopowder was synthesized by the coprecipitation method. FT-IR and EDS analyses were performed to qualitatively determine the composition of the nanopowder. FE-SEM images revealed the morphology of the nanopowder formed by clusters of nanoparticles. An XRD analysis confirmed the wurtzite structure with a crystallite size of ~21.2 nm. UV–Vis measurements were performed to determine the ZnO bandgap (~3.05 eV) using the Tauc plot method in the absorbance spectra. The ZnO nanopowder and two comb-like metal contacts were confined and compacted between two polymeric layers by a low-temperature thermal lamination method, resulting in a flexible Polymer/ZnO/Metal/ZnO/Polymer structure. Part of each comb-like metal was kept uncovered by a polymeric layer in order to be used for electrical characterization. I-V measurements of the flexible structure were performed in the dark and under UV illumination, showing the capacity to detect UV radiation and its potential application as a visible-blind UV sensor. A facile and low-cost flexible optoelectronic device is presented, avoiding using high-vacuum or high-temperature technology. This new and novel approach to developing optoelectronic devices proposes using powder materials as semiconducting active regions instead of thin films; this could eliminate the cracking and delamination problems of flexible devices based on thin film technology.