The Effect of SrO Addition on the Recrystallization of ZrSiO4 in Raw Glass–Ceramic Glazes from the SiO2-Al2O3-CaO-MgO-K2O-ZrO2 System

Author:

Partyka Janusz1ORCID,Pasiut Katarzyna1,Kozień Dawid1ORCID

Affiliation:

1. Department of Ceramics and Refractory Materials, Faculty of Materials Science and Technology, AGH University of Science and Technology, Mickiewicza Av. 30, 30-059 Krakow, Poland

Abstract

The aim of this experiment was to determine the effect of the addition of strontium oxide on the recrystallization of zirconium silicate when adding strontium oxide to the glaze composition. Zirconia glazes (four different contents) were prepared, to which strontium oxide was added in amounts of 0, 1, 3, 6, and 12 mass% SrO. The characteristic temperatures of the raw glazes were measured, based on which the maximum firing temperatures were determined. The fired glazes were subjected to a study of their phase compositions and an observation of their microstructures. An analysis of the characteristic temperatures showed a fluxing effect, but it was not as strong for all glazes. Differences in the amount of the crystalline phase of zirconium silicate obtained in the fired glazes, as well as the partial transition of zirconium silicate to the amorphous phase, were observed. Observations of the microstructure clearly indicated an increase in the homogeneity of the distribution of zirconium silicate.

Funder

Polish Ministry of Education and Science for the AGH University of Science and Technology in Krakow

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

Reference39 articles.

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4. Meija, J.F. (2004). Understanding the Role of Fluxes in Single-Fire Porcelain Glaze Development, Alfred University, Faculty of Ceramic Engineering, Kazuo Inamori School of Engineering.

5. Function and action of opacifiers;Kirk;J. Am. Ceram. Soc.,1932

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