Abstract
This paper is a literature survey that focuses on the present development of thermokinetic publications. It demonstrates that in recent years pyrolysis kinetics has turned into a major application of the thermokinetics. Analysis of the respective publications suggests that too often their quality leaves much to be desired because of the poor choices of the kinetic methods and experimental conditions. It is explained that the proper choices can be made by following the recommendations of the International Confederation for Thermal Analysis and Calorimetry (ICTAC). To help with improving the quality of the kinetic results, the ICTAC recommendations are condensed to a few easy to follow principles. These principles focus on selecting proper computational methods, collecting better experimental data, and efficiently reporting the results. The paramount computational principle is to avoid using the methods that evaluate the activation energy and other kinetic parameters from the data measured at a single heating rate. It is shown that the kinetic parameters evaluated by such methods can give rise to striking examples of failure when estimating the thermal stability at ambient temperature. Because of the vital importance of pyrolysis kinetics studies from an ecological and economical perspective, a substantial improvement of their quality is currently needed.
Funder
Russian Federal Ministry of Science and Higher Education
Subject
Building and Construction
Reference106 articles.
1. ICTAC Kinetics Committee Recommendations for Analysis of Thermal Polymerization Kinetics;Vyazovkin;Thermochim. Acta,2022
2. Kinetic Analysis of Crystallization Processes in Amorphous Materials;Thermochim. Acta,2000
3. Critical Review of the Global Chemical Kinetics of Cellulose Thermal Decomposition;Burnham;Energy Fuels,2015
4. Koga, N., Vyazovkin, S., Burnham, A.K., Favergeon, L., Muravyev, N.V., Perez-Maqueda, L.A., Saggese, C., and Sánchez-Jiménez, P.E. (2022). ICTAC Kinetics Committee Recommendations for Analysis of Thermal Decomposition Kinetics. Thermochim. Acta, 179384.
in press
.
5. Plastic Waste Recycling via Pyrolysis: A Bibliometric Survey and Literature Review;Armenise;J. Anal. Appl. Pyrolysis,2021
Cited by
26 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献