Development of High-Precision NO2 Gas Sensor Based on Non-Dispersive Infrared Technology

Author:

Zhao Yongmin12ORCID,Zhang Congchun12,Ci Guangteng12,Zhao Xiaoguang3ORCID,Lv Jinguang4ORCID,Liang Jingqiu4,Ming Anjie12ORCID,Wei Feng15,Mao Changhui15

Affiliation:

1. State Key Laboratory of Advanced Materials for Smart Sensing, GRINM Group Co., Ltd., Beijing 100088, China

2. Department of Advanced Electronic Materials, GRIMAT Engineering Institute Co., Ltd., Beijing 101407, China

3. Department of Precision Instrument, Tsinghua University, Beijing 100084, China

4. State Key Laboratory of Applied Optics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China

5. GRINM (Guangdong) Institute for Advanced Materials and Technology, Foshan 528000, China

Abstract

Increasing concerns about air quality due to fossil fuel combustion, especially nitrogen oxides (NOx) from marine and diesel engines, necessitate advanced monitoring systems due to the significant health and environmental impacts of nitrogen dioxide (NO2). In this study, a gas detection system based on the principle of the non-dispersive infrared (NDIR) technique is proposed. Firstly, the pyroelectric detector was developed by employing an ultra-thin LiTaO3 (LT) layer as the sensitive element, integrated with nanoscale carbon material prepared by wafer-level graphics technology as the infrared absorption layer. Then, the sensor was hermetically sealed using inert gas through energy storage welding technology, exhibiting a high detectivity (D*) value of 4.19 × 108 cm·√Hz/W. Subsequently, a NO2 gas sensor was engineered based on the NDIR principle employing a Micro Electro Mechanical System (MEMS) infrared (IR) emitter, featuring a light path chamber length of 1.5 m, along with integrated signal processing and software calibration algorithms. This gas sensor was capable of detecting NO2 concentrations within the range of 0–500 ppm. Initial tests indicated that the gas sensor exhibited a full-scale relative error of less than 0.46%, a limit of 2.8 ppm, a linearity of −1.09%, a repeatability of 0.47% at a concentration of 500 ppm, and a stability of 2% at a concentration of 500 ppm. The developed gas sensor demonstrated significant potential for application in areas such as industrial monitoring and analytical instrumentation.

Funder

National Natural Science Foundation of China

Shandong Provincial Key Research and Development program

Publisher

MDPI AG

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