Affiliation:
1. Water Research Institute (IRSA), National Research Council (CNR), Via F. de Blasio 5, 70132 Bari, Italy
2. Department of Chemistry, University of Bari Aldo Moro, Via Orabona 4, 70126 Bari, Italy
Abstract
AlCl3·6H2O was used as a catalyst in the esterification reaction of levulinic acid with 1-hexanol for producing hexyl levulinate, a compound that finds applications in several industrial sectors and represents an excellent candidate to be used in diesel fuel blends. A kinetic and thermodynamic study of the esterification reaction was performed, considering four different temperatures (338, 348, 358, and 368 K), an acid: alcohol: catalyst 1:1:0.01 molar ratio, and a reaction time of 72 h. An optimization study was then carried out, evaluating the effect of alcohol and catalyst amounts, and, in the best reaction conditions (acid:alcohol:catalyst 1:2:0.1), a very high levulinic acid conversion (92.5%) was achieved. By using AlCl3·6H2O, alongside the high reaction yield, the product purification was also simplified, being such a catalyst able to trap most of the water in a different phase than hexyl levulinate, and, furthermore, it was found to be completely recoverable and reusable for several reaction cycles, without losing its catalytic effectiveness. The use of AlCl3·6H2O, therefore, represents a promising effective green route for obtaining hexyl levulinate.
Reference44 articles.
1. Shukla, P.R., Slade, J.S., Al Khourdajie, A., van Diemen, R., McCollum, D., Pathak, M., Some, S., Vyas, P., Fradera, R., and Belkacemi, M. (2023). IPCC 2022: Climate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change, IPCC.
2. Monitoring Global Carbon Emissions in 2022;Liu;Nat. Rev. Earth Environ.,2023
3. Accelerating the Energy Transition to Achieve Carbon Neutrality;Guo;Resour. Conserv. Recycl.,2022
4. Recent Advances in Lignocellulosic and Algal Biomass Pretreatment and Its Biorefinery Approaches for Biochemicals and Bioenergy Conversion;Zhang;Bioresour. Technol.,2023
5. Strategies to Enhance Enzymatic Hydrolysis of Lignocellulosic Biomass for Biorefinery Applications: A Review;Saini;Bioresour. Technol.,2022