Novel Catalyst Composites of Ni- and Co-Based Nanoparticles Supported on Inorganic Oxides for Fatty Acid Hydrogenations

Author:

Mamontova Ekaterina1ORCID,Trabbia Corine1,Favier Isabelle1,Serrano-Maldonado Alejandro1ORCID,Ledeuil Jean-Bernard2,Madec Lénaïc2,Gómez Montserrat1ORCID,Pla Daniel1ORCID

Affiliation:

1. Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université Toulouse III—Paul Sabatier, 118 Route de Narbonne, CEDEX 9, 31062 Toulouse, France

2. E2S UPPA, CNRS, IPREM, Université de Pau et des Pays de l’Adour, 64053 Pau, France

Abstract

In the quest to develop nanometrically defined catalytic systems for applications in the catalytic valorization of agri-food wastes, small Ni-based nanoparticles supported on inorganic solid supports have been prepared by decomposition of organometallic precursors in refluxing ethanol under H2 atmosphere, in the presence of supports exhibiting insulating or semi-conductor properties, such as MgAl2O4 and TiO2, respectively. The efficiency of the as-prepared Ni-based nanocomposites has been evaluated towards the hydrogenation of unsaturated fatty acids under solvent-free conditions, with high selectivity regarding the hydrogenation of C=C bonds. The influence of the support on the catalytic performance of the prepared Ni-based nanocomposites is particularly highlighted.

Funder

POCTEFA Interreg program

Centre National de la Recherche Scientifique

the Université Toulouse III-Paul Sabatier

POCTEFA Interreg

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

Reference52 articles.

1. Action of nickel on ethylene. Ethane synthesis;Sabatier;C. R. Hebd. Seances Acad. Sci,1897

2. Action of hydrogen on acetylene in presence of nickel;Sabatier;C. R. Hebd. Seances Acad. Sci.,1899

3. Hydrogénations et déshydrogénations par catalyse;Sabatier;Ber. Dtsch. Chem. Ges.,1911

4. Sabatier, P. (1922). Catalysis in Organic Chemistry, D. Van Nostrand Company.

5. The nature of raney nickel, its adsorbed hydrogen and its catalytic activity for hydrogenation reactions (review);Fouilloux;Appl. Catal.,1983

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