Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping

Author:

Eremin Timofei1,Eremina Valentina1ORCID,Svirko Yuri1ORCID,Obraztsov Petr1ORCID

Affiliation:

1. Department of Physics and Mathematics, Center for Photonics Sciences, University of Eastern Finland, Yliopistokatu 2, 80101 Joensuu, Finland

Abstract

Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising way to improve their photoluminescent (PL) brightness and thus make them applicable as a base material for infrared light emitters. We report as high as over two-fold enhancement of the SWCNT PL brightness by using oxygen doping via the UV photodissociation of hypochlorite ions. By analyzing the temporal evolution of the PL and Raman spectra of SWCNTs in the course of the doping process, we conclude that the enhancement of SWCNTs PL brightness depends on the homogeneity of induced quantum defects distribution over the SWCNT surface.

Funder

Academy of Finland

Horizon 2020 RISE project DiSeTCom

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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