Parallel Factor Analysis with 3DEEMS of Dissolved Organic Matter from Deep Porous Medium Reservoirs in the City of Kaifeng

Abstract

The deep geothermal water found within Kaifeng City, Henan province, China, is mainly contained within a loose-pore geothermal reservoir in the Minghuazhen Formation (Neogene Period). To understand the role and composition of Dissolved Organic Matter (DOM) in geothermal water, water samples collected from 13 geothermal wells at different depths were studied using three-dimensional (3D) excitation-emission matrix-parallel factor (EEM-PARAFAC) analysis. Fluorescent components were analyzed according to depth, and DOM in geothermal water between 800 m and 1600 m was classified. The results show that the fluorescence index (FI), biological index (BIX), and humification index (HIX) of DOM differ among geothermal water from different thermal reservoirs. Based on these three indices, the humification degree of DOM in deep geothermal water in Kaifeng City is low and is mainly derived from an endogenous source, which is closely related to microbial activities in thermal reservoirs. The fluorescent components of DOM in geothermal water from depths less than 1200 m are mainly tryptophan, tyrosine, and fulvic acid-like. The fluorescent components of DOM in geothermal water from depths greater than 1200 m are more complex, with tryptophan, tyrosine, humic acid, and fulvic acid-like components. Therefore, the characteristics of DOM composition in the geothermal water from different reservoirs in Kaifeng can also be used to infer and explain that the quality of deep geothermal water has not been affected by human activities, and there is no obvious hydraulic connection between the geothermal water of each thermal reservoir.