An Analysis of Long-Process Ironmaking in a Reduction Smelting Furnace with Hydrogen-Enriched Conditions

Author:

Li Haifeng12ORCID,Chen Jingran2

Affiliation:

1. Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), Northeastern University, Shenyang 110819, China

2. School of Metallurgy, Northeastern University, Shenyang 110819, China

Abstract

The blast furnace and basic oxygen furnace (BF-BOF) is still the main process used for the production of iron and steel in China. With the approach of the “dual carbon” target, the iron and steel industry needs to transform and upgrade to “green” and “low-carbon” practices. At present, the low-carbon hydrogen metallurgy technology route based on hydrogen instead of carbon is mainly adopted at home and abroad, and the domestic route is mainly based on oxygen-rich BFs and hydrogen-based shaft furnaces (SFs). It promotes the transformation of the traditional BF to hydrogen-rich, oxygen-rich, and carbon-recycled (Hy-O-CR) technology. A new ironmaking system and method for a reduction smelting furnace (RSF) with Hy-O-CR is presented in this paper. The ironmaking system includes nine sets of equipment, such as an RSF, gas dust collector, dryer, CO2 separator, electrolytic water device, blower, heat exchanger, storage tank of reduction gas, and chimney. From top to bottom, the RSF includes an indirect reduction zone, a soft melting dripping zone, and a coke combustion zone. The ironmaking methods include coke and ore mixed charging, injection of the mixed reduction gas composed of electrolytic green hydrogen and circulating gas from the furnace gas into the indirect reduction zone, injection of oxygen into the coke combustion zone, CO2 recovery of the furnace top gas, and slag and iron treatment. By redesigning the size of the furnace type and optimizing the parameters, the metallization rate of the indirect reduction zone can be as high as 85–95%, and the carbon consumption per ton of hot metal can be greatly reduced. By using oxygen to recycle the reduction gas produced by its reactor, the process achieves the goal of reducing CO2 emissions by more than 50%, thus realizing green and low-carbon metallurgy.

Funder

National Key R&D Program of China

Fundamental Research Funds for the Central Universities

Publisher

MDPI AG

Subject

General Materials Science,Metals and Alloys

Reference46 articles.

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2. Zhang, P. (China Metallurgical News, 2022). Results of the world’s first 400 m3 industrial grade hydrogen-rich carbon circulating oxygen blast furnace released, China Metallurgical News, 172(A01). (In Chinese).

3. Li, H.F., Xu, W.R., Zhang, X.H., and Zou, Z.S. (2022, January 23–24). Theoretical analysis and practice of CO2 emission capability under hydrogen-rich fuel injection in blast furnace. Proceedings of the 13th China Iron and Steel Annual Meeting—Ironmaking and Raw Fuel, Beijing, China. (In Chinese).

4. Research on the application and development trend of hydrogen energy in iron and steel metallurgy;Lin;China Coal,2022

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