Diethyl 2-Cyano-3-oxosuccinate-Reference-Cited by-同舟云学术

Diethyl 2-Cyano-3-oxosuccinate

Published:2023-04-26 Issue:2 Volume:2023 Page:M1634
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

Markov Oleg N.¹,Moiseev Alexander E.¹,Tarasevich Boris N.¹,Tafeenko Victor A.¹,Beloglazkina Elena K.¹^ORCID,Shtil Alexander A.¹²,Finko Alexander V.¹³^ORCID

Affiliation:

1. Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia

2. Institute of Cyber Intelligence Systems, National Research Nuclear University MEPhI, 115409 Moscow, Russia

3. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russia

Abstract

The titular compound was characterized for the first time using a full range of spectroscopic methods, including UV, IR, 1H, and 13C NMR spectra. In solution, all methods showed a keto–enol equilibrium strongly shifted to the enol form. The X-ray structures determined for all simple 2-oxosuccinates showed only the enol form packed as hydrogen-bonded dimer stacks.

Funder

Russian Science Foundation

Publisher

MDPI AG

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://www.mdpi.com/1422-8599/2023/2/M1634/pdf

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