Unusual Catalytic Effect of Fe3+ on 2,4-dichlorophenoxyacetic Acid Degradation by Radio Frequency Discharge in Aqueous Solution

Author:

Liu Yongjun,Sun Bing

Abstract

2,4-dichlorophenoxyacetic acid (2,4-D) is a widely used herbicide for controlling broad-leaved weeds. The development of an efficient process for treating the refractory 2,4-D wastewater is necessary. In this study, liquid-phase degradation of 2,4-D induced by radio frequency discharge (RFD) was studied. Experimental results showed that the degradation was more effective in acidic than in neutral or alkaline solutions. During the degradation, a large amount of hydrogen peroxide (H2O2, 1.2 mM/min, almost equal to that without 2,4-D) was simultaneously produced, and catalytic effects of both ferric (Fe3+) and ferrous (Fe2+) ions on the degradation were examined and compared. It was found that 2,4-D degraded more rapidly in the case of Fe3+ than the that of Fe2+. Such a scenario is explained that Fe3+ was successively reduced to Fe2+ by the atomic hydrogen (•H) and •OH-adducts of 2,4-D resulting from RFD, which in turn catalyzed the H2O2 to form more •OH radicals through Fenton’s reaction, indicating that Fe3+ not only accelerates the degradation rate but also increases the amount of •OH available for 2,4-D degradation by suppressing the back reaction between the •H and •OH. 2,4-dichlorophenol, 4,6-dichlororesorcinol, 2-hydroxy-4-chloro- and 2-chloro-4-hydroxy- phenoxyacetic acids, hydroxylated 2,4-Ds, and carboxylic acids (glycolic, formic and oxalic) were identified as the byproducts. Energy yields of RFD have been compared with those of other nonthermal plasma processes.

Funder

National Natural Science Foundation of China

Publisher

MDPI AG

Subject

Water Science and Technology,Aquatic Science,Geography, Planning and Development,Biochemistry

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