Defense and Protection of the Marine Coastal Areas and Human Health: A Case Study of Asbestos Cement Contamination (Italy)

Author:

Somma Roberta1ORCID,Giacobbe Salvatore2,La Monica Francesco Paolo3,Molino Maria Letizia4,Morabito Marina2ORCID,Spoto Sebastiano Ettore1ORCID,Zaccaro Salvatore5,Zaffino Giuseppe3

Affiliation:

1. Department of Mathematical and Computer Sciences, Physical Sciences and Earth Sciences, University of Messina, Viale F. Stagno d’Alcontres, 31, Sant’Agata, 98166 Messina, Italy

2. Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Viale F. Stagno d’Alcontres, 31, Sant’Agata, 98166 Messina, Italy

3. Ambiente Lab, Granatari, 4, 98164 Messina, Italy

4. Metropolitan City of Messina, Palazzo dei Leoni, Corso Cavour, 98122 Messina, Italy

5. pH3 Engineering S.r.l., Via Caio Duilio, 2, 98123 Messina, Italy

Abstract

Pivotal environmental geology research was carried out in the protected area of Cape Peloro (Messina, NE Sicily, Italy). The main aims were the ascertainment of the presence of Asbestos Cement Materials (ACMs), their mapping, and, consequently, an estimation of the potential risk for human health and marine coastal environments. The beaches surveyed covered 4500 m of coastline. Through high-resolution photographic surveys, over 520 fiber cement fragments were documented on the beaches as well as in beach deposits. The materials, after microscope, SEM-EDS, and FTIR analyses, were found to be composed of Portland cement with chrysotile and crocidolite fibers. Fragments of ACMs showed typical corrugated forms with centimeter-to-decimeter sizes and prevailing well-rounded, platy, and sub-elongate shapes. In a few localities, some fragments were found to be angular or friable. Furthermore, some fragments found on the beach were covered by conspicuous encrustations of marine organisms, testifying to their long staying in shallow-water marine environments. Illicit landfills and abandoned materials were identified in natural sections on the coastal plain. Most of the rounded ACMs were characterized by their surface texture, with mm-size asbestos fibers exposed on the surface due to significant weathering and abrasion. Notably, new fragments appeared after storms. Significant criticisms have been made related to the ACMs, analogously to what was reported for other Italian marine beaches. Possible intervention and reclamation activities cannot limit themselves to removing the fragments on the beach, as fragments are immersed in the coastal sediments at different depths and are also found in the marine deposits. Here, it is underlined that any asbestos removal and reclamation activities, if not designed and based on a multidisciplinary approach and knowledge of local coastal dynamics and the meteo-marine climate, will be very expensive and ineffective.

Publisher

MDPI AG

Reference91 articles.

1. (2023, December 14). Directive (EU) 2023/2668 of the European Parliament and of the Council of 22 November 2023 Amending Directive 2009/148/EC on the Protection of Workers from the Risks Related to Exposure to Asbestos at Work. Available online: https://op.europa.eu/en/publication-detail/-/publication/bacbeacf-8f22-11ee-8aa6-01aa75ed71a1/language-en.

2. McCulloch, J., and Tweedale, G. (2008). Defending the Indefensible. The Global Asbestos Industry and Its Fight for Survival, Oxford University Press.

3. The experience of the Balangero chrysotile asbestos mine in Italy: Health effects among workers mining and milling asbestos and the health experience of persons living nearby;Silvestri;Can Miner.,2001

4. CAS (2023, December 14). A Division of the American Chemical Society. Available online: https://www.cas.org/cas-data/cas-registry.

5. Deer, W.A., Howie, R.A., and Zussman, J. (2013). An Introduction to the Rock-Forming Minerals, The Mineralogical Society. [3rd ed.].

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