Studies on the Processing of Fine Dusts from the Electric Smelting of Ilmenite Concentrates to Obtain Titanium Dioxide

Abstract

This article presents studies on the ammonium fluoride processing of dusts from the reduction smelting of ilmenite concentrate with separation of silicon to obtain titanium dioxide. Optimal conditions for pyrohydrolysis of titanium fluorides were determined. The effects of temperature and duration on the process were studied. The optimal conditions for pyrohydrolysis of titanium fluorides were a temperature of 600 °C and duration of 240–300 min. The degree of titanium fluoride conversion to titanium oxide was 99.5% at these conditions. Titanium dioxide obtained by pyrohydrolysis of titanium fluorides was purified from iron, chromium, and manganese impurities. The effect of hydrochloric acid solution concentration, S:L ratio, and the process duration on the purification degree of titanium fluoride pyrohydrolysis was studied. The following optimum purification conditions were determined: hydrochloric acid solution concentration 12.5–15 wt%, temperature 25–30 °C, S:L = 1:6÷8, duration 20–30 min. The purified titanium dioxide consisted mainly of anatase. The pigmented titanium dioxide of rutile modification with 99.8 wt% TiO2 was obtained after calcination at 900 °C for 120 min.