Abstract
Several binary metal diphosphinate compounds (ML) have been reported for diphosphinate bonded by a single methylene fragment. In case of longer bridges, binary products are difficult to isolate in crystalline form. Here, using a solvent assisted mechano-chemistry synthesis, we report two new ML crystalline phases, one hydrated and one anhydrous. The hydrated phase is a 2D coordination polymer with an open framework structure. Its network displays a new topology for coordination polymers and metal organic frameworks. The thermal behavior of the two phases has been studied. Finally, the importance of the bridge length is discussed in view of known metal diphosphinate compounds.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Reference45 articles.
1. Hybrid Organic-Inorganic Materials Based on Organophosphorus Derivatives;Vioux,2004
2. Recent Developments in Organophosphorus Flame Retardants Containing P-C Bond and Their Applications
3. Phosphinic Acid Based Linkers: Building Blocks in Metal-Organic Framework Chemistry
4. Hybrid Multifunctional Materials Based on Phosphonates, Phosphinates and Auxiliary Ligands;Costantino,2015
5. The Influence of Non-covalent Interactions in the Structure and Dimensionality of Hybrid Compounds and Coordination Polymers in Non-Covalent Interactions;Costantino,2016
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