Cyanogel-Induced Synthesis of RuPd Alloy Networks for High-Efficiency Formic Acid Oxidation

Abstract

For direct formic acid fuel cells (DFAFC), palladium (Pd)-based alloy catalysts with competitive morphology and elemental composition are essential to boost the performance of the formic acid oxidation reaction (FAOR) in the anode zone. Herein, we design and synthesize RuPdx alloy nano-network structures (ANs) via the facile wet-chemical reduction of Pd-Ru cyanogel (Pdx [Ru(CN)6]y·aH2O) as an effective electrocatalyst for the FAOR. The formation of Pd-Ru cyanogel depends on the facile coordination of K2PdCl4 and K3 [Ru(CN)6]. The unique structure of cyanogel ensures the presentation of a three-dimensional mesoporous morphology and the homogeneity of the elemental components. The as-prepared RuPd3 ANs exhibit good electrocatalytic activity and stability for the FAOR. Notably, the RuPd3 ANs achieve a mass-specific activity of 2068.4 mA mg−1 in FAOR, which shows an improvement of approximately 16.9 times compared to Pd black. Such a competitive FAOR performance of RuPd3 ANs can be attributed to the advantages of structure and composition, which facilitate the exposure of more active sites, accelerate mass/electron transfer rates, and promote gas escape from the catalyst layer, as well as enhance chemical stability.