Mild Fenton Processes for the Removal of Preservatives: Interfering Effect of Methylisothiazolinone (MIT) on Paraben Degradation

Abstract

The degradation of various preservatives used in the cosmetics industry, including five parabens and their most employed substitute, methylisothiazolinone (MIT), was investigated. A mild photo-Fenton process was applied using low iron concentrations (5 mg/L) at a pH of five, instead of the traditional acidic value of three. At these conditions, the paraben degradation was very low after one hour of reaction and it was necessary to present humic-like substances (HLS) acting as iron chelators to improve the process. Values obtained when MIT was treated were very low, also in the presence of HLS, indicating that their complexing effect was not acting properly. When MIT was added to the mixture of parabens an inhibitory effect was found in the presence of HLS. A possible complex between iron and MIT was suggested and the studies of hydrogen peroxide consumption and Job’s plot technique confirmed this hypothesis. Evidence of the formation of this inactive complex, so far never reported, will be essential in future work when dealing with this compound using Fenton processes. Furthermore, this fact points out the importance of using mixtures of model contaminants instead of a single one or a group of the same family, since their ability to form active or inactive complexes with iron can strongly change the behavior of the whole system.