Egg-Shell-Type MgAl2O4 Pellet Catalyst for Steam Methane Reforming Reaction Activity: Effect of Pellet Preparation Temperature

Abstract

A pellet catalyst was prepared to be used in a large-scale steam methane reformer. Hydrotalcite powder (MG30) was used as a precursor to prepare MgAl2O4 pellet supports at different calcination temperatures. Ni-supported catalysts with egg-shell-type distribution were prepared on these pellet supports: Ni/sup-x (where x is the calcination temperature of the support with x = 1273, 1373, and 1473 K). Among them, Ni/sup-1473, which experienced the highest calcination temperature (1473 K), showed the highest methane conversion and lowest weight loss owing to carbon deposition. As a result, when the calcination temperature increased, the egg-shell thickness decreased, and the reducibility of the catalyst was enhanced. Although a small amount of Ni (3.5 wt%) was used, the egg-shell-type catalyst had superior catalytic activity and coke resistance. Therefore, the egg-shell-type catalyst using Ni as the active material and MgAl2O4 calcined at high temperature as the support is expected to be appropriate for large-scale industrial steam methane reforming reactions.