Production of Ceramics/Metal Oxide Nanofibers via Electrospinning: New Insights into the Photocatalytic and Bactericidal Mechanisms

Author:

Algethami Jari S.12ORCID,Amna Touseef3ORCID,S. Alqarni Laila4,Alshahrani Aisha A.5,Alhamami Mohsen A. M.1,Seliem Amal F.1,Al-Dhuwayin Badria H. A.1,Hassan M. Shamshi5ORCID

Affiliation:

1. Department of Chemistry, College of Science and Arts, Najran University, Najran 11001, Saudi Arabia

2. Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, Najran 11001, Saudi Arabia

3. Department of Biology, College of Science, Al-Baha University, Albaha 65799, Saudi Arabia

4. Department of Chemistry, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh 11432, Saudi Arabia

5. Department of Chemistry, College of Science, Al-Baha University, Albaha 65799, Saudi Arabia

Abstract

Environmental pollution is steadily rising and is having a negative influence on all living things, especially human beings. The advancement of nanoscience in recent decades has provided potential to address this issue. Functional metal oxide nanoparticles/nanofibers have been having a pull-on effect in the biological and environmental domains of nanobiotechnology. Current work, for the first time, is focusing on the electrospinning production of Zr0.5Sn0.5TiO3/SnO2 ceramic nanofibers that may be utilized to battle lethal infections swiftly and inexpensively. By using characterizations like XRD, FT–IR, FESEM, TEM, PL, and UV–Vis–DRS, the composition, structure, morphology, and optical absorption of samples were determined. The minimum inhibitory concentration (MIC) approach was used to investigate the antibacterial activity. Notably, this research indicated that nanofibers exert antibacterial action against both Gram-positive and Gram-negative bacteria with a MIC of 25 µg/mL. Furthermore, negatively charged E. coli was drawn to positively charged metal ions of Zr0.5Sn0.5TiO3/SnO2, which showed a robust inhibitory effect against E. coli. It was interesting to discover that, compared to pure TiO2, Zr0.5Sn0.5TiO3/SnO2 nanofibers revealed increased photocatalytic activity and exceptional cyclability to the photodegradation of Rhodamine B. The composite completely degrades dye in 30 min with 100% efficacy and excellent (97%) reusability. The synergetic effects of Zr0.5Sn0.5TiO3 and SnO2 may be responsible for increased photocatalytic and bactericidal activity.

Funder

Deputy for Research and Innovation Ministry of Education, Kingdom of Saudi Arabia

Publisher

MDPI AG

Subject

General Materials Science

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