High-Strength Building Material Based on a Glass Concrete Binder Obtained by Mechanical Activation

Author:

Dobrosmyslov Sergey S.12,Zadov Vladimir E.1,Nazirov Rashit A.2,Shakirova Veronika A.2,Voronin Anton S.12ORCID,Simunin Michail M.12ORCID,Fadeev Yuri V.12,Molokeev Maxim S.34ORCID,Shabanova Ksenia A.1,Khartov Stanislav V.1

Affiliation:

1. Federal Research Center Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences (FRC KSC SB RAS), 660036 Krasnoyarsk, Russia

2. School of Engineering and Construction, Siberian Federal University, 660041 Krasnoyarsk, Russia

3. Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center, Siberian Branch, Russian Academy of Sciences, 660036 Krasnoyarsk, Russia

4. Laboratory of Theory and Optimization of Chemical and Technological Processes, University of Tyumen, 625003 Tyumen, Russia

Abstract

As part of the work, the chemical interaction of finely ground glass (~1 μm), calcium oxide, and water was studied. It is shown that an increase in the fineness of grinding makes it possible to abandon autoclave hardening in the production of products on a hydrosilicate binder. The study of chemical interaction was carried out by calculating the thermodynamic equilibrium and was also confirmed by XRD analysis. DTA analysis showed that an increase in the treatment temperature leads to an increase in the proportion of the reacted phase at the first stage. Subsequently, phase formation is associated with the presence of CaO. The carrier of strength characteristics is the CaO×2SiO2×2H2O phase. The selection and optimization of the composition make it possible to obtain a high-strength glass concrete material with a strength of about 110 MPa. The micrographs of the obtained samples correspond to classical hydrosilicate systems.

Publisher

MDPI AG

Subject

Building and Construction,Civil and Structural Engineering,Architecture

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