The Influence of Boron Doping on the Structures and Composition of Dicalcium Silicate: A Research Study

Author:

Zhang Da’an12,Zhou Hao2ORCID,Kang Guodong2,Zhang Shenghu2,Zhang Cheng2,Yan Xiaofei2,Ma Bing2,Zhang Houhu2

Affiliation:

1. Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, 219 Ningliu Road, Nanjing 210044, China

2. Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of the People’s Republic of China, Nanjing 210042, China

Abstract

This paper investigates the structural transformation of dicalcium silicate (C2S) crystals brought about through boron doping. Both qualitative and quantitative analyses were conducted to explore the correspondence between boron content and the structure of dicalcium silicate. The results show that boron doping can stabilize β-C2S and the high-temperature phase α′H-C2S, and the structural transformation does not involve the modulation of α′L-C2S. There is a corresponding relationship between the unit cells of β-C2S and α′H-C2S, which can be transformed using a transformation matrix. The relationship between boron content and the content of different C2S structures, as well as the structural expressions for β-C2S and α′H-C2S, is determined using linear fitting and multivariable linear regression analysis.

Funder

Special Fund of Chinese Central Government for Basic Scientific Research Operations in commonweal Research Institute

Special Fund of Carbon Peak and Carbon Neutrality Research Institute supported by Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment

Publisher

MDPI AG

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