Physical and Chemical Phenomena during the Production of Hydrogen in the Microwave Discharge Generated in Liquid Hydrocarbons with the Barbotage of Various Gases-Reference-Cited by-同舟云学术

Physical and Chemical Phenomena during the Production of Hydrogen in the Microwave Discharge Generated in Liquid Hydrocarbons with the Barbotage of Various Gases

Published:2023-07-31 Issue:8 Volume:11 Page:2292
ISSN:2227-9717
Container-title:Processes
language:en
Short-container-title:Processes

Author:

Batukaev Timur¹^ORCID,Bilera Igor¹^ORCID,Krashevskaya Galina¹²,Lebedev Yuri¹^ORCID

Affiliation:

1. A.V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences (TIPS RAS), Leninsky Ave., 29, Moscow 119991, Russia

2. Institute LAPLAZ, National Research Nuclear University MEPhI, Kashirskoe Shosse, 31, Moscow 115409, Russia

Abstract

The physical and chemical characteristics of the microwave discharge in petroleum solvent during hydrogen production processes involving Ar, He, and CO2 barbotage were studied. Gas chromatography, emission spectroscopy, high-speed photography, and shadow photography were used for diagnosis. The results demonstrated the dependence of hydrogen yield on the flow rates of Ar, He, and CO2. The maximum yield values of hydrogen were 791 mL/min and 811 mL/min, while the maximum energy efficiency reached 135.6 NL/kWh and 162.2 NL/kWh in Nefras with Ar and He barbotage, respectively. The dynamics of discharge structure and the rotational and vibrational temperatures of C2 molecules were studied.

Publisher

MDPI AG

Subject

Process Chemistry and Technology,Chemical Engineering (miscellaneous),Bioengineering

Link

https://www.mdpi.com/2227-9717/11/8/2292/pdf

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