5-Vinyl-1H-tetrazole-Reference-Cited by-同舟云学术

5-Vinyl-1H-tetrazole

Published:2023-01-23 Issue:1 Volume:2023 Page:M1565
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

Krygina Daria M.¹,Sivtsov Eugene V.²,Pavlyukova Yuliya N.³,Chernova Ekaterina N.⁴^ORCID,Skryl’nikova Mariya A.³⁵,Baigildin Vadim A.⁶,Puzyk Aleksandra M.⁷^ORCID,Oskorbyn Alexander A.²,Trifonov Rostislav E.³,Aleshunin Pavel A.³,Ostrovskii Vladimir A.³⁴^ORCID

Affiliation:

1. Laboratory of Polymer Sorbents and Carriers for Biotechnology, Institute of Macromolecular Compounds, Russian Academy of Sciences (IMC RAS), 31 Bolshoy Prospekt V.O., 199004 St. Petersburg, Russia

2. Department of Physical Chemistry, Saint Petersburg State Institute of Technology, 24–26/49 Moskovsky Ave., 190013 St. Petersburg, Russia

3. Department of Chemistry and Technology of Nitrogen-Containing Organic Compounds, Saint Petersburg State Institute of Technology, 24–26/49 Moskovsky Ave., 190013 St. Petersburg, Russia

4. Saint Petersburg Federal Research Center, Russian Academy of Sciences (SPC RAS), 39, 14th Line, 199178 St. Petersburg, Russia

5. Department of Organic Chemistry, Saint Petersburg State Institute of Technology, 24–26/49 Moskovsky Ave., 190013 St. Petersburg, Russia

6. Department of General and Inorganic Chemistry, Institute of Chemistry, Saint Petersburg State University, 26 Universitetskii Prospect, Petergof, 198504 St. Petersburg, Russia

7. Research Park, Saint Petersburg State University, 26 Universitetskii Prospect, Petergof, 198504 St. Petersburg, Russia

Abstract

Highly purified 5-vinyl-1H-tetrazole was synthesized, which is in great demand in modern medicine and industry as a monomer for obtaining nitrogen-rich macromolecular compounds and a reagent for the complete synthesis of biological compounds. The molecular structure was studied experimentally with sequential X-ray diffraction analysis and theoretically with ab initio quantum chemical calculations. The data from differential scanning calorimetry, nuclear magnetic resonance (1H, 13C, 1H-15N, HMBC), high-resolution mass spectrometry and vibrational spectroscopy were analyzed. The results are useful for evaluating the possibility of extending the polymerization of 5-vinyl-1H-tetrazole to synthesize polymers with predictable molecular weight and thermodynamic parameters.

Funder

Russian Foundation for Basic Research and the Committee on Science of the Republic of Armenia

young scientists FASIE

Ministry of Science and Higher Education of the Russian Federation

Publisher

MDPI AG

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://www.mdpi.com/1422-8599/2023/1/M1565/pdf

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